| 13. Round | 04/11/2006 | Celtic FC | - | Heart of Midlothian | 2:1 | ||||
| 14. Round | 13/11/2006 | Falkirk FC | - | Heart of Midlothian | 1:1 |  |
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| 15. Round | 19/11/2006 | Heart of Midlothian | - | Rangers FC | 0:1 | ||||
| 16. Round | 25/11/2006 | Inverness CT | - | Heart of Midlothian | 0:0 | |
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| 18. Round | 09/12/2006 | Heart of Midlothian | - | Motherwell FC | 4:1 | |
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| 19. Round | 16/12/2006 | Heart of Midlothian | - | Aberdeen FC | 0:1 | ||||
| 20. Round | 23/12/2006 | Dundee United | - | Heart of Midlothian | 0:1 | |
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| 21. Round | 26/12/2006 | Heart of Midlothian | - | Hibernian FC | 3:2 | ||||
| 23. Round | 02/01/2007 | Dunfermline Athletic | - | Heart of Midlothian | 0:1 | ||||
| 24. Round | 14/01/2007 | Heart of Midlothian | - | Celtic FC | 1:2 |
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