| 1. Round | 26/08/2012 | US Palermo | - | SSC Napoli | 0:3 |  |
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| 2. Round | 02/09/2012 | Lazio Roma | - | US Palermo | 3:0 | ||||
| 3. Round | 15/09/2012 | US Palermo | - | Cagliari Calcio | 1:1 | ||||
| 7. Round | 06/10/2012 | Genoa CFC | - | US Palermo | 1:1 | ||||
| 9. Round | 27/10/2012 | AC Siena | - | US Palermo | 0:0 | |
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| 11. Round | 04/11/2012 | AS Roma | - | US Palermo | 4:1 | ||||
| 12. Round | 11/11/2012 | US Palermo | - | Sampdoria | 2:0 |
Argentina
Italy