| 8. Round | 02/10/2021 | Queen Of The South | - | Dunfermline Athletic | 1:0 | ||||
| 9. Round | 16/10/2021 | Dunfermline Athletic | - | Kilmarnock FC | 2:2 | ||||
| 10. Round | 23/10/2021 | Partick Thistle | - | Dunfermline Athletic | 0:0 | ||||
| 11. Round | 26/10/2021 | Dunfermline Athletic | - | Raith Rovers | 1:1 | ||||
| 12. Round | 30/10/2021 | Arbroath FC | - | Dunfermline Athletic | 4:2 | ||||
| 13. Round | 06/11/2021 | Dunfermline Athletic | - | Greenock Morton FC | 1:3 | ||||
| 15. Round | 20/11/2021 | Dunfermline Athletic | - | Ayr United | 3:0 | ||||
| 19. Round | 26/12/2021 | Dunfermline Athletic | - | Arbroath FC | 0:3 | ||||
| 21. Round | 02/01/2022 | Raith Rovers | - | Dunfermline Athletic | 0:0 | ||||
| 22. Round | 08/01/2022 | Greenock Morton FC | - | Dunfermline Athletic | 5:0 | ||||
| 23. Round | 15/01/2022 | Dunfermline Athletic | - | Hamilton Academical | 1:0 |  |
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| 20. Round | 22/01/2022 | Dunfermline Athletic | - | Inverness CT | 1:1 | |
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| 26. Round | 22/03/2022 | Dunfermline Athletic | - | Partick Thistle | 4:1 |
Scotland