| Group H | 06/09/2022 | SL Benfica | - | Maccabi Haifa | 2:0 |  |
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| Group H | 14/09/2022 | Juventus | - | SL Benfica | 1:2 | ||||
| Group H | 05/10/2022 | SL Benfica | - | Paris Saint-Germain | 1:1 | ||||
| Group H | 11/10/2022 | Paris Saint-Germain | - | SL Benfica | 1:1 | ||||
| Group H | 25/10/2022 | SL Benfica | - | Juventus | 4:3 | |
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| Group H | 02/11/2022 | Maccabi Haifa | - | SL Benfica | 1:6 | |
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| Round of 16 | 15/02/2023 | Club Brugge KV | - | SL Benfica | 0:2 | ||||
| Round of 16 | 07/03/2023 | SL Benfica | - | Club Brugge KV | 5:1 | |
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| Quarter-finals | 11/04/2023 | SL Benfica | - | Inter | 0:2 | ||||
| Quarter-finals | 19/04/2023 | Inter | - | SL Benfica | 3:3 |  |
Portugal