| 3. Round | 19/08/2013 | Jong PSV | - | FC Oss | 4:0 | ||||
| 4. Round | 24/08/2013 | De Graafschap | - | Jong PSV | 3:0 |  |
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| 5. Round | 30/08/2013 | FC Dordrecht | - | Jong PSV | 2:0 | ||||
| 6. Round | 02/09/2013 | Jong PSV | - | Jong Ajax | 2:4 |  |
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| 7. Round | 08/09/2013 | Willem II | - | Jong PSV | 2:0 | |
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| 8. Round | 16/09/2013 | Jong PSV | - | Fortuna Sittard | 0:0 | ||||
| 9. Round | 20/09/2013 | FC Den Bosch | - | Jong PSV | 2:1 | ||||
| 11. Round | 06/10/2013 | Achilles'29 | - | Jong PSV | 3:2 | ||||
| 12. Round | 14/10/2013 | Jong PSV | - | FC Volendam | 3:0 | |
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| 13. Round | 18/10/2013 | Helmond Sport | - | Jong PSV | 1:1 | ||||
| 14. Round | 28/10/2013 | Jong PSV | - | Telstar | 3:1 | ||||
| 15. Round | 03/11/2013 | VVV-Venlo | - | Jong PSV | 0:2 | ||||
| 16. Round | 11/11/2013 | Jong PSV | - | MVV | 3:2 | |
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| 17. Round | 16/11/2013 | FC Emmen | - | Jong PSV | 0:2 | |
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| 19. Round | 02/12/2013 | Jong PSV | - | FC Eindhoven | 1:2 | ||||
| 21. Round | 16/12/2013 | Jong PSV | - | FC Dordrecht | 3:0 | ||||
| 22. Round | 20/12/2013 | FC Oss | - | Jong PSV | 1:2 | ||||
| 23. Round | 20/01/2014 | Jong PSV | - | De Graafschap | 0:2 | ||||
| 24. Round | 26/01/2014 | SBV Excelsior | - | Jong PSV | 2:1 | |
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