| Relegation | 27/05/19 | 1. FC Union Berlin | - | VfB Stuttgart | 0:0 | ||||
| Bundesliga | 04/04/21 | 1. FC Union Berlin | - | Hertha BSC | 1:1 |  |
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| Bundesliga | 20/11/21 | 1. FC Union Berlin | - | Hertha BSC | 2:0 | ||||
| DFB-Pokal | 19/01/22 | Hertha BSC | - | 1. FC Union Berlin | 2:3 | ||||
| Bundesliga | 09/04/22 | Hertha BSC | - | 1. FC Union Berlin | 1:4 |
| Santiago Lionel Ascacíbar | |
| Born: | 25.02.1997 |
| Place of birth: |
La Plata, Buenos Aires, 
Argentina |
| Nationality: |
Argentina
Italy |
| Height: | 169 cm |
| Weight: | 70 kg |
| Position(s): | Defensive Midfielder Central Midfielder |
| Foot: | right |
