| 1. Round | 30/07/2022 | Stenhousemuir FC | - | Albion Rovers | 1:0 | ||||
| 2. Round | 06/08/2022 | Albion Rovers | - | Dumbarton FC | 1:2 |  |
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| 3. Round | 13/08/2022 | Albion Rovers | - | East Fife FC | 0:1 | |
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| 4. Round | 20/08/2022 | Bonnyrigg Rose Athletic | - | Albion Rovers | 0:2 | |
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| 5. Round | 27/08/2022 | Albion Rovers | - | Annan Athletic | 2:2 | ||||
| 6. Round | 03/09/2022 | Stirling Albion FC | - | Albion Rovers | 1:1 | |
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| 7. Round | 11/10/2022 | Elgin City | - | Albion Rovers | 1:0 | ||||
| 11. Round | 15/10/2022 | Dumbarton FC | - | Albion Rovers | 1:1 | ||||
| 24. Round | 11/02/2023 | Albion Rovers | - | East Fife FC | 0:1 | ||||
| 17. Round | 21/02/2023 | Albion Rovers | - | Elgin City | 3:0 | ||||
| 26. Round | 25/02/2023 | Albion Rovers | - | Annan Athletic | 0:2 | ||||
| 27. Round | 04/03/2023 | Stirling Albion FC | - | Albion Rovers | 3:2 | ||||
| 29. Round | 18/03/2023 | Dumbarton FC | - | Albion Rovers | 1:5 | ||||
| 28. Round | 21/03/2023 | Albion Rovers | - | Stranraer FC | 0:1 | ||||
| 30. Round | 25/03/2023 | Albion Rovers | - | Bonnyrigg Rose Athletic | 0:1 |
Scotland