| 1. Round | 25/08/2012 | Levadiakos | - | Panathinaikos | 0:1 | ||||
| 2. Round | 02/09/2012 | Olympiakos Piraeus | - | Levadiakos | 4:0 | ||||
| 3. Round | 15/09/2012 | Levadiakos | - | Veria FC | 0:0 | ||||
| 4. Round | 22/09/2012 | Levadiakos | - | Panionios GSS | 3:0 | ||||
| 5. Round | 01/10/2012 | PAS Giannina | - | Levadiakos | 1:0 |  |
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| 6. Round | 08/10/2012 | Levadiakos | - | Panthrakikos | 0:3 | ||||
| 11. Round | 18/11/2012 | OFI Heraklion | - | Levadiakos | 0:2 | ||||
| 12. Round | 24/11/2012 | AEK Athen | - | Levadiakos | 0:1 |  |
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| 13. Round | 02/12/2012 | Levadiakos | - | AO Kerkyra | 2:0 | ||||
| 15. Round | 16/12/2012 | Levadiakos | - | Platanias Chanion | 1:0 |
Italy