| 4. Round | 10/11/2013 | Rio Ave FC | - | Sertanense FC | 4:2 |  |
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| Round of 16 | 04/01/2014 | Rio Ave FC | - | Vitória Setúbal | 1:0 | ||||
| Quarter-finals | 06/02/2014 | Rio Ave FC | - | Académica de Coimbra | 1:0 | |
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| Semi-finals | 26/03/2014 | Sporting Braga | - | Rio Ave FC | 0:0 | ||||
| Semi-finals | 16/04/2014 | Rio Ave FC | - | Sporting Braga | 2:0 |
Portugal