| 6. Round | 09/09/2006 | Heart of Midlothian | - | St. Mirren FC | 0:1 | ||||
| 7. Round | 16/09/2006 | St. Mirren FC | - | Kilmarnock FC | 0:1 | ||||
| 8. Round | 23/09/2006 | Dunfermline Athletic | - | St. Mirren FC | 2:1 | ||||
| 9. Round | 30/09/2006 | St. Mirren FC | - | Hibernian FC | 1:0 | ||||
| 10. Round | 14/10/2006 | Falkirk FC | - | St. Mirren FC | 1:1 | ||||
| 11. Round | 22/10/2006 | St. Mirren FC | - | Rangers FC | 2:3 | ||||
| 12. Round | 28/10/2006 | St. Mirren FC | - | Inverness CT | 1:1 | ||||
| 13. Round | 04/11/2006 | Motherwell FC | - | St. Mirren FC | 0:0 | ||||
| 14. Round | 12/11/2006 | St. Mirren FC | - | Celtic FC | 1:3 | ||||
| 15. Round | 18/11/2006 | Aberdeen FC | - | St. Mirren FC | 2:0 | ||||
| 16. Round | 26/11/2006 | Dundee United | - | St. Mirren FC | 1:0 | ||||
| 17. Round | 02/12/2006 | St. Mirren FC | - | Heart of Midlothian | 2:2 | ||||
| 18. Round | 09/12/2006 | Kilmarnock FC | - | St. Mirren FC | 1:1 | ||||
| 19. Round | 16/12/2006 | St. Mirren FC | - | Dunfermline Athletic | 0:0 | ||||
| 20. Round | 23/12/2006 | Hibernian FC | - | St. Mirren FC | 5:1 | ||||
| 22. Round | 30/12/2006 | Rangers FC | - | St. Mirren FC | 1:1 | ||||
| 23. Round | 01/01/2007 | Inverness CT | - | St. Mirren FC | 2:1 |
England