| 1. Round | 03/10/2020 | Espanyol Barcelona [Women] | - | Atlético Madrid [Women] | 0:2 | ||||
| 5. Round | 04/11/2020 | UDG Tenerife Sur [Women] | - | Espanyol Barcelona [Women] | 2:0 | ||||
| 16. Round | 14/02/2021 | Rayo Vallecano [Women] | - | Espanyol Barcelona [Women] | 2:0 | ||||
| 23. Round | 20/03/2021 | SD Eibar [Women] | - | Espanyol Barcelona [Women] | 0:1 | ||||
| 24. Round | 28/03/2021 | Espanyol Barcelona [Women] | - | Real Sociedad [Women] | 0:4 | ||||
| 25. Round | 04/04/2021 | Real Betis [Women] | - | Espanyol Barcelona [Women] | 0:0 | ||||
| 26. Round | 17/04/2021 | Espanyol Barcelona [Women] | - | Rayo Vallecano [Women] | 2:2 | ||||
| 27. Round | 25/04/2021 | Sporting de Huelva [Women] | - | Espanyol Barcelona [Women] | 2:1 |
Argentina