| 7. Round | 01/10/2022 | Getafe CF | - | Real Valladolid | 2:3 | ||||
| 8. Round | 09/10/2022 | Real Valladolid | - | Real Betis | 0:0 | ||||
| 9. Round | 16/10/2022 | Espanyol Barcelona | - | Real Valladolid | 1:0 |  |
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| 10. Round | 19/10/2022 | Real Valladolid | - | RC Celta | 4:1 | ||||
| 11. Round | 22/10/2022 | Real Valladolid | - | Real Sociedad | 1:0 | ||||
| 12. Round | 30/10/2022 | CA Osasuna | - | Real Valladolid | 2:0 | ||||
| 14. Round | 08/11/2022 | Athletic Club | - | Real Valladolid | 3:0 | ||||
| 16. Round | 07/01/2023 | RCD Mallorca | - | Real Valladolid | 1:0 |
Morocco
Spain 
