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| 1st(1st leg) | Azuriz - PR | - | Operário Ferroviário - PR | 1:0 (1:0) | ||
| 2nd (2nd leg) | Operário Ferroviário - PR | - | Azuriz - PR | 4:3 (1:0) pso | ||
| 1st(1st leg): 17/05/2021 18:00 | 2nd (2nd leg): 20/05/2021 20:00 | Winner: Operário Ferroviário - PR | ||||
| 1st(1st leg) | Maringá - PR | - | Cascavel FC - PR | 1:2 (1:1) | ||
| 2nd (2nd leg) | Cascavel FC - PR | - | Maringá - PR | 1:1 (0:0) | ||
| 1st(1st leg): 17/05/2021 18:00 | 2nd (2nd leg): 20/05/2021 20:00 | Winner: Cascavel FC - PR | ||||
| 1st(1st leg) | Londrina - PR | - | Cianorte - PR | 1:1 (1:0) | ||
| 2nd (2nd leg) | Cianorte - PR | - | Londrina - PR | 0:3 (0:3) | ||
| 1st(1st leg): 17/05/2021 18:00 | 2nd (2nd leg): 20/05/2021 20:00 | Winner: Londrina - PR | ||||
| 1st(1st leg) | Paraná Clube | - | Athletico Paranaense | 0:2 (0:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Paraná Clube | 0:0 (0:0) | ||
| 1st(1st leg): 24/05/2021 19:20 | 2nd (2nd leg): 16/06/2021 19:20 | Winner: Athletico Paranaense | ||||
