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| 1st(1st leg) | Volta Redonda - RJ | - | Bahia - BA | 1:2 (0:1) | ||
| 2nd (2nd leg) | Bahia - BA | - | Volta Redonda - RJ | 4:0 (0:0) | ||
| 1st(1st leg): 11/04/2023 20:30 | 2nd (2nd leg): 27/04/2023 23:00 | Winner: Bahia - BA | ||||
| 1st(1st leg) | Botafogo - SP | - | Santos FC | 0:2 (0:2) | ||
| 2nd (2nd leg) | Santos FC | - | Botafogo - SP | 1:0 (0:0) | ||
| 1st(1st leg): 11/04/2023 23:00 | 2nd (2nd leg): 26/04/2023 23:00 | Winner: Santos FC | ||||
| 1st(1st leg) | Internacional | - | CSA - AL | 2:1 (1:1) | ||
| 2nd (2nd leg) | CSA - AL | - | Internacional | 6:7 (1:0, 2:1) pso | ||
| 1st(1st leg): 12/04/2023 00:00 | 2nd (2nd leg): 28/04/2023 00:00 | Winner: Internacional | ||||
| 1st(1st leg) | São Paulo FC | - | Ituano - SP | 0:0 (0:0) | ||
| 2nd (2nd leg) | Ituano - SP | - | São Paulo FC | 0:1 (0:0) | ||
| 1st(1st leg): 12/04/2023 01:30 | 2nd (2nd leg): 26/04/2023 01:30 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Fortaleza | - | Águia de Marabá - PA | 6:1 (3:0) | ||
| 2nd (2nd leg) | Águia de Marabá - PA | - | Fortaleza | 0:2 (0:2) | ||
| 1st(1st leg): 12/04/2023 01:30 | 2nd (2nd leg): 26/04/2023 23:30 | Winner: Fortaleza | ||||
| 1st(1st leg) | Nova Iguaçu - RJ | - | América - MG | 1:2 (0:0) | ||
| 2nd (2nd leg) | América - MG | - | Nova Iguaçu - RJ | 5:0 (0:0) | ||
| 1st(1st leg): 12/04/2023 20:30 | 2nd (2nd leg): 27/04/2023 01:30 | Winner: América - MG | ||||
| 1st(1st leg) | Coritiba - PR | - | Sport Recife - PE | 3:3 (2:1) | ||
| 2nd (2nd leg) | Sport Recife - PE | - | Coritiba - PR | 2:0 (1:0) | ||
| 1st(1st leg): 12/04/2023 23:00 | 2nd (2nd leg): 26/04/2023 23:00 | Winner: Sport Recife - PE | ||||
| 1st(1st leg) | Fluminense RJ | - | Paysandu - PA | 3:0 (3:0) | ||
| 2nd (2nd leg) | Paysandu - PA | - | Fluminense RJ | 0:3 (0:2) | ||
| 1st(1st leg): 12/04/2023 23:30 | 2nd (2nd leg): 26/04/2023 00:00 | Winner: Fluminense RJ | ||||
| 1st(1st leg) | CR Brasil - AL | - | Athletico Paranaense | 1:0 (0:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | CR Brasil - AL | 4:2 (0:1, 2:1) pso | ||
| 1st(1st leg): 12/04/2023 23:30 | 2nd (2nd leg): 26/04/2023 01:30 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Palmeiras | - | Tombense - MG | 4:2 (2:1) | ||
| 2nd (2nd leg) | Tombense - MG | - | Palmeiras | 1:1 (0:1) | ||
| 1st(1st leg): 13/04/2023 00:00 | 2nd (2nd leg): 27/04/2023 00:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Atlético Mineiro | - | Brasil de Pelotas - RS | 2:1 (0:0) | ||
| 2nd (2nd leg) | Brasil de Pelotas - RS | - | Atlético Mineiro | 1:1 (1:0) | ||
| 1st(1st leg): 13/04/2023 01:30 | 2nd (2nd leg): 26/04/2023 23:30 | Winner: Atlético Mineiro | ||||
| 1st(1st leg) | Ypiranga - RS | - | Botafogo - RJ | 0:2 (0:1) | ||
| 2nd (2nd leg) | Botafogo - RJ | - | Ypiranga - RS | 2:0 (1:0) | ||
| 1st(1st leg): 13/04/2023 01:30 | 2nd (2nd leg): 27/04/2023 23:30 | Winner: Botafogo - RJ | ||||
| 1st(1st leg) | Remo - PA | - | Corinthians SP | 2:0 (1:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Remo - PA | 5:4 (1:0, 2:0) pso | ||
| 1st(1st leg): 13/04/2023 01:30 | 2nd (2nd leg): 27/04/2023 01:30 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Náutico - PE | - | Cruzeiro | 1:0 (0:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | Náutico - PE | 2:0 (0:0) | ||
| 1st(1st leg): 13/04/2023 23:00 | 2nd (2nd leg): 25/04/2023 23:00 | Winner: Cruzeiro | ||||
| 1st(1st leg) | Maringá - PR | - | Flamengo RJ | 2:0 (1:0) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Maringá - PR | 8:2 (4:1) | ||
| 1st(1st leg): 14/04/2023 00:00 | 2nd (2nd leg): 27/04/2023 01:30 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | ABC - RN | - | Grêmio Porto Alegre | 0:2 (0:0) | ||
| 2nd (2nd leg) | Grêmio Porto Alegre | - | ABC - RN | 1:1 (0:1) | ||
| 1st(1st leg): 14/04/2023 01:30 | 2nd (2nd leg): 28/04/2023 01:30 | Winner: Grêmio Porto Alegre | ||||
