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| 1st(1st leg) | Vitória - ES | - | Ceilândia - DF | 1:0 (1:0) | ||
| 2nd (2nd leg) | Ceilândia - DF | - | Vitória - ES | 3:0 (2:0) | ||
| 1st(1st leg): 29/07/2023 19:00 | 2nd (2nd leg): 05/08/2023 19:30 | Winner: Ceilândia - DF | ||||
| 1st(1st leg) | Maranhão - MA | - | Tuna Luso - PA | 2:3 (1:1) | ||
| 2nd (2nd leg) | Tuna Luso - PA | - | Maranhão - MA | 4:5 (0:0, 0:1) pso | ||
| 1st(1st leg): 29/07/2023 20:00 | 2nd (2nd leg): 06/08/2023 20:00 | Winner: Maranhão - MA | ||||
| 1st(1st leg) | Inter de Limeira - SP | - | S.E.R. Caxias - RS | 0:1 (0:0) | ||
| 2nd (2nd leg) | S.E.R. Caxias - RS | - | Inter de Limeira - SP | 1:1 (1:1) | ||
| 1st(1st leg): 29/07/2023 20:00 | 2nd (2nd leg): 06/08/2023 19:00 | Winner: S.E.R. Caxias - RS | ||||
| 1st(1st leg) | Falcon - SE | - | Sousa - PB | 1:1 (0:0) | ||
| 2nd (2nd leg) | Sousa - PB | - | Falcon - SE | 2:1 (0:1) | ||
| 1st(1st leg): 29/07/2023 20:00 | 2nd (2nd leg): 06/08/2023 20:00 | Winner: Sousa - PB | ||||
| 1st(1st leg) | Camboriú - SC | - | Maringá - PR | 0:0 (0:0) | ||
| 2nd (2nd leg) | Maringá - PR | - | Camboriú - SC | 5:6 (1:1) pso | ||
| 1st(1st leg): 29/07/2023 21:00 | 2nd (2nd leg): 06/08/2023 23:00 | Winner: Camboriú - SC | ||||
| 1st(1st leg) | Ferroviária - SP | - | Hercílio Luz - SC | 1:1 (1:0) | ||
| 2nd (2nd leg) | Hercílio Luz - SC | - | Ferroviária - SP | 2:4 (0:1) pso | ||
| 1st(1st leg): 29/07/2023 21:00 | 2nd (2nd leg): 05/08/2023 19:00 | Winner: Ferroviária - SP | ||||
| 1st(1st leg) | ASA - AL | - | Nacional - PB | 1:0 (0:0) | ||
| 2nd (2nd leg) | Nacional - PB | - | ASA - AL | 3:1 (2:0) | ||
| 1st(1st leg): 29/07/2023 21:00 | 2nd (2nd leg): 06/08/2023 20:00 | Winner: Nacional - PB | ||||
| 1st(1st leg) | Parnahyba - PI | - | Nacional - AM | 2:0 (2:0) | ||
| 2nd (2nd leg) | Nacional - AM | - | Parnahyba - PI | 3:0 (2:0) | ||
| 1st(1st leg): 30/07/2023 19:00 | 2nd (2nd leg): 06/08/2023 20:00 | Winner: Nacional - AM | ||||
| 1st(1st leg) | Brasil de Pelotas - RS | - | Atlético Patrocinense - MG | 0:0 (0:0) | ||
| 2nd (2nd leg) | Atlético Patrocinense - MG | - | Brasil de Pelotas - RS | 2:1 (0:0) | ||
| 1st(1st leg): 30/07/2023 20:00 | 2nd (2nd leg): 06/08/2023 15:00 | Winner: Atlético Patrocinense - MG | ||||
| 1st(1st leg) | Operário - MT | - | Portuguesa - RJ | 1:0 (1:0) | ||
| 2nd (2nd leg) | Portuguesa - RJ | - | Operário - MT | 4:0 (2:0) | ||
| 1st(1st leg): 30/07/2023 20:00 | 2nd (2nd leg): 05/08/2023 20:00 | Winner: Portuguesa - RJ | ||||
| 1st(1st leg) | Brasiliense - DF | - | Athletic - MG | 0:2 (0:1) | ||
| 2nd (2nd leg) | Athletic - MG | - | Brasiliense - DF | 0:0 (0:0) | ||
| 1st(1st leg): 30/07/2023 20:00 | 2nd (2nd leg): 05/08/2023 19:00 | Winner: Athletic - MG | ||||
| 1st(1st leg) | Pacajus - CE | - | Retrô - PE | 1:2 (0:1) | ||
| 2nd (2nd leg) | Retrô - PE | - | Pacajus - CE | 2:1 (2:1) | ||
| 1st(1st leg): 30/07/2023 21:00 | 2nd (2nd leg): 06/08/2023 22:00 | Winner: Retrô - PE | ||||
| 1st(1st leg) | Potiguar de Mossoró - RN | - | Bahia de Feira - BA | 1:0 (0:0) | ||
| 2nd (2nd leg) | Bahia de Feira - BA | - | Potiguar de Mossoró - RN | 7:6 (0:0) pso | ||
| 1st(1st leg): 30/07/2023 21:00 | 2nd (2nd leg): 05/08/2023 21:00 | Winner: Bahia de Feira - BA | ||||
| 1st(1st leg) | Águia de Marabá - PA | - | Atlético Cearense - CE | 1:1 (1:1) | ||
| 2nd (2nd leg) | Atlético Cearense - CE | - | Águia de Marabá - PA | 3:0 (1:0) | ||
| 1st(1st leg): 01/08/2023 00:00 | 2nd (2nd leg): 06/08/2023 19:00 | Winner: Atlético Cearense - CE | ||||
| 1st(1st leg) | Democrata Gov. Valadares - MG | - | Anápolis FC - GO | 0:0 (0:0) | ||
| 2nd (2nd leg) | Anápolis FC - GO | - | Democrata Gov. Valadares - MG | 3:1 (2:1) | ||
| 1st(1st leg): 01/08/2023 00:30 | 2nd (2nd leg): 06/08/2023 20:00 | Winner: Anápolis FC - GO | ||||
| 1st(1st leg) | Princesa do Solimões - AM | - | Ferroviário - CE | 1:1 (0:0) | ||
| 2nd (2nd leg) | Ferroviário - CE | - | Princesa do Solimões - AM | 3:0 (1:0) | ||
| 1st(1st leg): 01/08/2023 01:00 | 2nd (2nd leg): 05/08/2023 21:00 | Winner: Ferroviário - CE | ||||
