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| 1st(1st leg) | Audax Italiano | - | Universidad Católica | 1:0 | ||
| 2nd (2nd leg) | Universidad Católica | - | Audax Italiano | 0:3 | ||
| 1st(1st leg): 25/11/2006 | 2nd (2nd leg): 03/12/2006 | Winner: Audax Italiano | ||||
| 1st(1st leg) | Coquimbo Unido | - | O'Higgins | 0:0 | ||
| 2nd (2nd leg) | O'Higgins | - | Coquimbo Unido | 2:1 | ||
| 1st(1st leg): 25/11/2006 | 2nd (2nd leg): 02/12/2006 | Winner: O'Higgins | ||||
| 1st(1st leg) | Colo-Colo | - | Puerto Montt | 1:0 | ||
| 2nd (2nd leg) | Puerto Montt | - | Colo-Colo | 0:4 | ||
| 1st(1st leg): 26/11/2006 | 2nd (2nd leg): 06/12/2006 | Winner: Colo-Colo | ||||
| 1st(1st leg) | Universidad de Chile | - | Cobreloa | 1:0 | ||
| 2nd (2nd leg) | Cobreloa | - | Universidad de Chile | 3:1 | ||
| 1st(1st leg): 26/11/2006 | 2nd (2nd leg): 03/12/2006 | Winner: Cobreloa | ||||
