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| 1st(1st leg) | River Plate | - | Boca Juniors | 2:1 (1:1) | ||
| 2nd (2nd leg) | Boca Juniors | - | River Plate | 3:0 (0:0) | ||
| 1st(1st leg): 17/05/2000 | 2nd (2nd leg): 24/05/2000 | Winner: Boca Juniors | ||||
| 1st(1st leg) | CF América | - | Bolívar | 2:0 (0:0) | ||
| 2nd (2nd leg) | Bolívar | - | CF América | 1:2 (0:1) | ||
| 1st(1st leg): 17/05/2000 | 2nd (2nd leg): 25/05/2000 | Winner: CF América | ||||
| 1st(1st leg) | Atlético Mineiro | - | Corinthians SP | 1:1 (0:1) | ||
| 2nd (2nd leg) | Corinthians SP | - | Atlético Mineiro | 2:1 (2:0) | ||
| 1st(1st leg): 18/05/2000 | 2nd (2nd leg): 23/05/2000 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Atlas Guadalajara | - | Palmeiras | 0:2 (0:1) | ||
| 2nd (2nd leg) | Palmeiras | - | Atlas Guadalajara | 3:2 (1:1) | ||
| 1st(1st leg): 18/05/2000 | 2nd (2nd leg): 25/05/2000 | Winner: Palmeiras | ||||
