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| 1st(1st leg) | Peñarol | - | Universidad Católica | 2:0 (1:0) | ||
| 2nd (2nd leg) | Universidad Católica | - | Peñarol | 2:1 (1:0) | ||
| 1st(1st leg): 11/05/2011 23:30 | 2nd (2nd leg): 20/05/2011 00:00 | Winner: Peñarol | ||||
| 1st(1st leg) | Once Caldas | - | Santos FC | 0:1 (0:1) | ||
| 2nd (2nd leg) | Santos FC | - | Once Caldas | 1:1 (1:1) | ||
| 1st(1st leg): 12/05/2011 01:50 | 2nd (2nd leg): 19/05/2011 02:00 | Winner: Santos FC | ||||
| 1st(1st leg) | Vélez Sarsfield | - | Libertad | 3:0 (1:0) | ||
| 2nd (2nd leg) | Libertad | - | Vélez Sarsfield | 2:4 (1:1) | ||
| 1st(1st leg): 13/05/2011 00:15 | 2nd (2nd leg): 18/05/2011 23:30 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Jaguares Chiapas | - | Cerro Porteño | 1:1 (0:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Jaguares Chiapas | 1:0 (0:0) | ||
| 1st(1st leg): 13/05/2011 02:45 | 2nd (2nd leg): 20/05/2011 02:30 | Winner: Cerro Porteño | ||||
