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| 1st(1st leg) | Bolívar | - | Santos FC | 2:1 (1:1) | ||
| 2nd (2nd leg) | Santos FC | - | Bolívar | 8:0 (5:0) | ||
| 1st(1st leg): 26/04/2012 01:50 | 2nd (2nd leg): 10/05/2012 23:30 | Winner: Santos FC | ||||
| 1st(1st leg) | Internacional | - | Fluminense RJ | 0:0 (0:0) | ||
| 2nd (2nd leg) | Fluminense RJ | - | Internacional | 2:1 (2:1) | ||
| 1st(1st leg): 26/04/2012 01:50 | 2nd (2nd leg): 11/05/2012 02:00 | Winner: Fluminense RJ | ||||
| 1st(1st leg) | Atlético Nacional | - | Vélez Sarsfield | 0:1 (0:1) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Atlético Nacional | 1:1 (0:0) | ||
| 1st(1st leg): 02/05/2012 01:15 | 2nd (2nd leg): 09/05/2012 00:00 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Cruz Azul | - | Libertad | 1:1 (1:0) | ||
| 2nd (2nd leg) | Libertad | - | Cruz Azul | 2:0 (1:0) | ||
| 1st(1st leg): 02/05/2012 03:30 | 2nd (2nd leg): 09/05/2012 02:30 | Winner: Libertad | ||||
| 1st(1st leg) | Boca Juniors | - | Unión Española | 2:1 (1:0) | ||
| 2nd (2nd leg) | Unión Española | - | Boca Juniors | 2:3 (0:1) | ||
| 1st(1st leg): 02/05/2012 23:30 | 2nd (2nd leg): 09/05/2012 23:30 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Emelec | - | Corinthians SP | 0:0 (0:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Emelec | 3:0 (1:0) | ||
| 1st(1st leg): 03/05/2012 01:50 | 2nd (2nd leg): 10/05/2012 02:00 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Vasco da Gama - RJ | - | Lanús | 2:1 (2:0) | ||
| 2nd (2nd leg) | Lanús | - | Vasco da Gama - RJ | 4:5 (0:1, 2:1, 2:1) pso | ||
| 1st(1st leg): 03/05/2012 01:50 | 2nd (2nd leg): 10/05/2012 02:00 | Winner: Vasco da Gama - RJ | ||||
| 1st(1st leg) | Deportivo Quito | - | Universidad de Chile | 4:1 (2:1) | ||
| 2nd (2nd leg) | Universidad de Chile | - | Deportivo Quito | 6:0 (3:0) | ||
| 1st(1st leg): 04/05/2012 01:15 | 2nd (2nd leg): 11/05/2012 02:00 | Winner: Universidad de Chile | ||||
