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| 1st(1st leg) | Deportivo Guadalajara | - | Atlético Nacional | 1:1 (0:0) | ||
| 2nd (2nd leg) | Atlético Nacional | - | Deportivo Guadalajara | 4:2 (2:2, 3:3, 3:3) pso | ||
| 1st(1st leg): 18/10/2000 | 2nd (2nd leg): 25/10/2000 | Winner: Atlético Nacional | ||||
| 1st(1st leg) | Emelec | - | Millonarios | 3:3 (2:2) | ||
| 2nd (2nd leg) | Millonarios | - | Emelec | 2:0 (1:0) | ||
| 1st(1st leg): 19/10/2000 | 2nd (2nd leg): 26/10/2000 | Winner: Millonarios | ||||
