Friendlies Clubs   M. W D L goals
  at home 1 1 0 0 2 : 1
  Neutral Place 1 0 0 1 0 : 1
  2 1 0 1 2 : 2
Champions League   M. W D L goals
  at home 1 0 1 0 1 : 1
  Away 1 0 0 1 0 : 1
  2 0 1 1 1 : 2
Europa League   M. W D L goals
  at home 1 0 1 0 1 : 1
  Away 1 0 0 1 2 : 4
  2 0 1 1 3 : 5
overall   M. W D L goals
  at home 3 1 2 0 4 : 3
  Away 2 0 0 2 2 : 5
  Neutral Place 1 0 0 1 0 : 1
  6 1 2 3 6 : 9
Friendlies Clubs
2018 Week PSV Eindhoven - Valencia CF 2:1 (2:1)
2015 Week Valencia CF - PSV Eindhoven 1:0
Champions League
1999/2000 Preliminary Gr. F Valencia CF - PSV Eindhoven 1:0 (0:0)
1999/2000 Preliminary Gr. F PSV Eindhoven - Valencia CF 1:1 (0:1)
Europa League
2011/2012 Round of 16 PSV Eindhoven - Valencia CF 1:1 (0:0)
2011/2012 Round of 16 Valencia CF - PSV Eindhoven 4:2 (3:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking