| WC Qualifiers Africa | M. | W | D | L | goals | |||
| at home | 1 | 0 | 0 | 1 | 0 | : | 1 | |
| Away | 1 | 0 | 0 | 1 | 0 | : | 8 | |
| ∑ | 2 | 0 | 0 | 2 | 0 | : | 9 | |
| Africa Cup Qual. | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 2 | : | 1 | |
| Neutral Place | 1 | 0 | 0 | 1 | 0 | : | 4 | |
| ∑ | 2 | 1 | 0 | 1 | 2 | : | 5 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 1 | 0 | 1 | 2 | : | 2 | |
| Away | 1 | 0 | 0 | 1 | 0 | : | 8 | |
| Neutral Place | 1 | 0 | 0 | 1 | 0 | : | 4 | |
| ∑ | 4 | 1 | 0 | 3 | 2 | : | 14 | |
| WC Qualifiers Africa | |||||
| 2004/2005 | 1. Round | Libya | - | São Tomé and Príncipe | 8:0 (4:0) |
| 2004/2005 | 1. Round | São Tomé and Príncipe | - | Libya | 0:1 (0:0) |
| Africa Cup Qual. | |||||
| 2015/2016 | Group F | Libya | - | São Tomé and Príncipe | 4:0 (0:0) |
| 2015/2016 | Group F | São Tomé and Príncipe | - | Libya | 2:1 (0:1) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
CAF ![São Tomé and Príncipe [Women]](https://s.hs-data.com/bilder/wappen/mini/2613.gif?fallback=png "São Tomé and Príncipe [Women]"){kind=small}
![São Tomé and Príncipe [U18]](https://s.hs-data.com/bilder/wappen/mini/32021.gif?fallback=png "São Tomé and Príncipe [U18]"){kind=small}