| 3. Round | 28/08/2024 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 6. Round | 22/09/2024 | Athletic Club | - | RC Celta | 3:1 | ||||
| 9. Round | 06/10/2024 | Girona FC | - | Athletic Club | 2:1 | ||||
| 10. Round | 19/10/2024 | Athletic Club | - | Espanyol Barcelona | 4:1 | ||||
| 13. Round | 10/11/2024 | Real Valladolid | - | Athletic Club | 1:1 | ||||
| 19. Round | 04/12/2024 | Athletic Club | - | Real Madrid | 2:1 | ||||
| 17. Round | 15/12/2024 | CD Alavés | - | Athletic Club | 1:1 |  |
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| 20. Round | 19/01/2025 | RC Celta | - | Athletic Club | 1:2 | ||||
| 21. Round | 26/01/2025 | Athletic Club | - | CD Leganés | 0:0 | ||||
| 22. Round | 02/02/2025 | Real Betis | - | Athletic Club | 2:2 | ||||
| 23. Round | 08/02/2025 | Athletic Club | - | Girona FC | 3:0 | ||||
| 27. Round | 09/03/2025 | Athletic Club | - | RCD Mallorca | 1:1 | ||||
| 30. Round | 06/04/2025 | Villarreal CF | - | Athletic Club | 0:0 | ||||
| 31. Round | 13/04/2025 | Athletic Club | - | Rayo Vallecano | 3:1 | |
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| 32. Round | 20/04/2025 | Real Madrid | - | Athletic Club | 1:0 | ||||
| 34. Round | 04/05/2025 | Real Sociedad | - | Athletic Club | 0:0 | ||||
| 36. Round | 15/05/2025 | Getafe CF | - | Athletic Club | 0:2 | ||||
| 37. Round | 18/05/2025 | Valencia CF | - | Athletic Club | 0:1 | |
Senegal