| #1 | 06/06/1962 | Brazil | - | Spain | 2:1 |  |
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| #2 | 01/11/1962 | Spain | - | Romania | 6:0 | ||||
| #3 | 02/12/1962 | Belgium | - | Spain | 1:1 | ||||
| #4 | 09/01/1963 | Spain | - | France | 0:0 | ||||
| #5 | 30/05/1963 | Spain | - | Northern Ireland | 1:1 | ||||
| #6 | 13/06/1963 | Spain | - | Scotland | 2:6 | |
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| #7 | 01/12/1963 | Spain | - | Belgium | 1:2 | ||||
| #8 | 05/05/1965 | Ireland | - | Spain | 1:0 | ||||
| #9 | 08/12/1965 | Spain | - | England | 0:2 | ||||
| #10 | 23/06/1966 | Spain | - | Uruguay | 1:1 | ||||
| #11 | 20/07/1966 | Germany | - | Spain | 2:1 | ||||
| #12 | 31/05/1967 | Spain | - | Turkey | 2:0 | ||||
| #13 | 01/10/1967 | CSSR | - | Spain | 1:0 | ||||
| #14 | 28/10/1970 | Spain | - | Greece | 2:1 |
Spain