| 1. Round | 29/09/1940 | Hércules CF | - | Real Murcia | 4:0 | ||||
| 2. Round | 06/10/1940 | Real Madrid | - | Hércules CF | 5:3 | ||||
| 3. Round | 13/10/1940 | Hércules CF | - | Athletic Club | 1:0 | ||||
| 5. Round | 27/10/1940 | Hércules CF | - | Valencia CF | 0:2 | ||||
| 6. Round | 03/11/1940 | Real Zaragoza | - | Hércules CF | 7:0 | ||||
| 7. Round | 10/11/1940 | Sevilla FC | - | Hércules CF | 8:3 | ||||
| 9. Round | 24/11/1940 | Espanyol Barcelona | - | Hércules CF | 1:2 |  |
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| 10. Round | 01/12/1940 | Hércules CF | - | Real Oviedo | 3:0 | ||||
| 12. Round | 15/12/1940 | Real Murcia | - | Hércules CF | 0:0 | ||||
| 13. Round | 22/12/1940 | Hércules CF | - | Real Madrid | 0:3 | ||||
| 14. Round | 29/12/1940 | Athletic Club | - | Hércules CF | 4:0 | ||||
| 15. Round | 05/01/1941 | Hércules CF | - | FC Barcelona | 1:3 | ||||
| 17. Round | 26/01/1941 | Hércules CF | - | Real Zaragoza | 1:0 | ||||
| 18. Round | 02/02/1941 | Hércules CF | - | Sevilla FC | 1:0 | ||||
| 19. Round | 09/02/1941 | Atlético Aviación | - | Hércules CF | 7:1 | ||||
| 20. Round | 16/02/1941 | Hércules CF | - | Espanyol Barcelona | 3:2 | ||||
| 21. Round | 23/02/1941 | Real Oviedo | - | Hércules CF | 6:0 | ||||
| 22. Round | 02/03/1941 | Hércules CF | - | RC Celta | 0:5 |
Spain