| 1. Round | 13/08/2023 | Villarreal CF | - | Real Betis | 1:2 |  |
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| 6. Round | 24/09/2023 | Rayo Vallecano | - | Villarreal CF | 1:1 | ||||
| 7. Round | 27/09/2023 | Villarreal CF | - | Girona FC | 1:2 | ||||
| 8. Round | 30/09/2023 | Getafe CF | - | Villarreal CF | 0:0 | ||||
| 9. Round | 08/10/2023 | Villarreal CF | - | UD Las Palmas | 1:2 | ||||
| 10. Round | 22/10/2023 | Villarreal CF | - | CD Alavés | 1:1 | ||||
| 12. Round | 05/11/2023 | Villarreal CF | - | Athletic Club | 2:3 | |
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| 17. Round | 17/12/2023 | Real Madrid | - | Villarreal CF | 4:1 | ||||
| 18. Round | 20/12/2023 | Villarreal CF | - | RC Celta | 3:2 |  |
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| 22. Round | 27/01/2024 | FC Barcelona | - | Villarreal CF | 3:5 | ||||
| 27. Round | 03/03/2024 | Villarreal CF | - | Granada CF | 5:1 | ||||
| 28. Round | 10/03/2024 | Real Betis | - | Villarreal CF | 2:3 | ||||
| 29. Round | 17/03/2024 | Villarreal CF | - | Valencia CF | 1:0 | |
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| 30. Round | 01/04/2024 | Villarreal CF | - | Atlético Madrid | 1:2 | ||||
| 32. Round | 21/04/2024 | UD Almería | - | Villarreal CF | 1:2 | ||||
| 38. Round | 25/05/2024 | CA Osasuna | - | Villarreal CF | 1:1 |
France
