| 3. Round | 29/08/2022 | Cádiz CF | - | Athletic Club | 0:4 | ||||
| 6. Round | 17/09/2022 | Athletic Club | - | Rayo Vallecano | 3:2 | ||||
| 7. Round | 30/09/2022 | Athletic Club | - | UD Almería | 4:0 | ||||
| 17. Round | 14/01/2023 | Real Sociedad | - | Athletic Club | 3:1 | ||||
| 18. Round | 22/01/2023 | Athletic Club | - | Real Madrid | 0:2 | ||||
| 21. Round | 11/02/2023 | Valencia CF | - | Athletic Club | 1:2 | ||||
| 22. Round | 19/02/2023 | Atlético Madrid | - | Athletic Club | 1:0 | ||||
| 23. Round | 26/02/2023 | Athletic Club | - | Girona FC | 2:3 |  |
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| 28. Round | 08/04/2023 | Espanyol Barcelona | - | Athletic Club | 1:2 | ||||
| 32. Round | 01/05/2023 | RCD Mallorca | - | Athletic Club | 1:1 | ||||
| 33. Round | 04/05/2023 | Athletic Club | - | Real Betis | 0:1 | ||||
| 34. Round | 13/05/2023 | Villarreal CF | - | Athletic Club | 5:1 | |
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| 35. Round | 20/05/2023 | Athletic Club | - | RC Celta | 2:1 | |
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| 36. Round | 25/05/2023 | CA Osasuna | - | Athletic Club | 2:0 | ||||
| 37. Round | 28/05/2023 | Athletic Club | - | Elche CF | 0:1 | ||||
| 38. Round | 04/06/2023 | Real Madrid | - | Athletic Club | 1:1 |
Spain