| Round of 16 | 04/01/2006 | Villarreal CF | - | Valencia CF | 0:2 | ||||
| Round of 16 | 11/01/2006 | Valencia CF | - | Villarreal CF | 1:0 |  |
| Round of 16 | 04/01/2006 | Villarreal CF | - | Valencia CF | 0:2 | ||||
| Round of 16 | 11/01/2006 | Valencia CF | - | Villarreal CF | 1:0 | |
| Carlos Alcántara Cuevas | |
| Born: | 01.02.1985 |
| Place of birth: |
Zarandona, 
Spain |
| Nationality: |
Spain
|
| Height: | 178 cm |
| Weight: | 73 kg |
| Position(s): | Left Back |
| Foot: | left |