| 5. Round | 20/09/2021 | FC Barcelona | - | Granada CF | 1:1 | ||||
| 12. Round | 30/10/2021 | FC Barcelona | - | CD Alavés | 1:1 | ||||
| 13. Round | 06/11/2021 | RC Celta | - | FC Barcelona | 3:3 | ||||
| 18. Round | 18/12/2021 | FC Barcelona | - | Elche CF | 3:2 | ||||
| 37. Round | 15/05/2022 | Getafe CF | - | FC Barcelona | 0:0 |
| 5. Round | 20/09/2021 | FC Barcelona | - | Granada CF | 1:1 | ||||
| 12. Round | 30/10/2021 | FC Barcelona | - | CD Alavés | 1:1 | ||||
| 13. Round | 06/11/2021 | RC Celta | - | FC Barcelona | 3:3 | ||||
| 18. Round | 18/12/2021 | FC Barcelona | - | Elche CF | 3:2 | ||||
| 37. Round | 15/05/2022 | Getafe CF | - | FC Barcelona | 0:0 |
| Alejandro Alberto Balde Martínez | |
| Born: | 18.10.2003 |
| Place of birth: |
Barcelona, 
Spain |
| Nationality: |
Spain
Dom. Republic |
| Height: | 175 cm |
| Weight: | 69 kg |
| Position(s): | Left Back Left Midfielder |
| Foot: | left |
