| 1. Round | 12/11/2022 | CD Santa Amalia | - | Villarreal CF | 0:9 |  |
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| 2. Round | 20/12/2022 | CD Guijuelo | - | Villarreal CF | 1:2 aet | ||||
| 3. Round | 03/01/2023 | FC Cartagena | - | Villarreal CF | 1:5 | |
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| Round of 16 | 19/01/2023 | Villarreal CF | - | Real Madrid | 2:3 |  |
| 1. Round | 12/11/2022 | CD Santa Amalia | - | Villarreal CF | 0:9 | |
|||
| 2. Round | 20/12/2022 | CD Guijuelo | - | Villarreal CF | 1:2 aet | ||||
| 3. Round | 03/01/2023 | FC Cartagena | - | Villarreal CF | 1:5 | |
|||
| Round of 16 | 19/01/2023 | Villarreal CF | - | Real Madrid | 2:3 | |
| Alejandro Baena Rodríguez | |
| Born: | 20.07.2001 |
| Place of birth: |
Roquetas de Mar, 
Spain |
| Nationality: |
Spain
|
| Height: | 174 cm |
| Weight: | 69 kg |
| Position(s): | Left Midfielder Offensive Midfielder |
| Foot: | right |
