| 1. Round | 30/08/1991 | Athletic Club | - | Sevilla FC | 0:2 | ||||
| 3. Round | 13/09/1991 | Athletic Club | - | Real Madrid | 1:4 |  |
|||
| 9. Round | 09/11/1991 | Athletic Club | - | Espanyol Barcelona | 0:2 | ||||
| 10. Round | 15/11/1991 | Real Sociedad | - | Athletic Club | 2:0 | |
|||
| 11. Round | 23/11/1991 | Athletic Club | - | Real Zaragoza | 1:0 | ||||
| 12. Round | 30/11/1991 | Real Oviedo | - | Athletic Club | 1:1 | |
|||
| 13. Round | 07/12/1991 | Athletic Club | - | Atlético Madrid | 3:2 | ||||
| 14. Round | 14/12/1991 | CA Osasuna | - | Athletic Club | 1:1 |  |
|||
| 15. Round | 20/12/1991 | Athletic Club | - | Valencia CF | 2:3 | ||||
| 28. Round | 28/03/1992 | Espanyol Barcelona | - | Athletic Club | 2:0 | ||||
| 29. Round | 03/04/1992 | Athletic Club | - | Real Sociedad | 2:1 | ||||
| 33. Round | 02/05/1992 | Athletic Club | - | CA Osasuna | 2:1 | ||||
| 34. Round | 08/05/1992 | Valencia CF | - | Athletic Club | 3:1 | |
|||
| 35. Round | 16/05/1992 | Athletic Club | - | CD Tenerife | 3:1 | |
|||
| 36. Round | 23/05/1992 | Cádiz CF | - | Athletic Club | 1:0 | |
|||
| 37. Round | 30/05/1992 | Athletic Club | - | Real Valladolid | 2:0 | ||||
| 38. Round | 06/06/1992 | FC Barcelona | - | Athletic Club | 2:0 |
Spain