| 3. Round | 28/08/2024 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 4. Round | 31/08/2024 | Athletic Club | - | Atlético Madrid | 0:1 | ||||
| 7. Round | 19/09/2024 | CD Leganés | - | Athletic Club | 0:2 | ||||
| 6. Round | 22/09/2024 | Athletic Club | - | RC Celta | 3:1 |  |
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| 9. Round | 06/10/2024 | Girona FC | - | Athletic Club | 2:1 | ||||
| 10. Round | 19/10/2024 | Athletic Club | - | Espanyol Barcelona | 4:1 | ||||
| 11. Round | 28/10/2024 | RCD Mallorca | - | Athletic Club | 0:0 | ||||
| 12. Round | 03/11/2024 | Athletic Club | - | Real Betis | 1:1 | ||||
| 13. Round | 10/11/2024 | Real Valladolid | - | Athletic Club | 1:1 | ||||
| 14. Round | 24/11/2024 | Athletic Club | - | Real Sociedad | 1:0 | ||||
| 15. Round | 01/12/2024 | Rayo Vallecano | - | Athletic Club | 1:2 | ||||
| 17. Round | 15/12/2024 | CD Alavés | - | Athletic Club | 1:1 | ||||
| 22. Round | 02/02/2025 | Real Betis | - | Athletic Club | 2:2 | ||||
| 31. Round | 13/04/2025 | Athletic Club | - | Rayo Vallecano | 3:1 |  |
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| 32. Round | 20/04/2025 | Real Madrid | - | Athletic Club | 1:0 | ||||
| 34. Round | 04/05/2025 | Real Sociedad | - | Athletic Club | 0:0 | ||||
| 35. Round | 11/05/2025 | Athletic Club | - | CD Alavés | 1:0 | |
Spain
Guinea-Bissau