| 1. Round | 11/09/1966 | Hércules CF | - | CE Sabadell | 0:0 | ||||
| 8. Round | 06/11/1966 | Real Madrid | - | Hércules CF | 2:1 | ||||
| 9. Round | 13/11/1966 | Hércules CF | - | UD Las Palmas | 2:1 | ||||
| 10. Round | 20/11/1966 | Hércules CF | - | Athletic Club | 1:2 |  |
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| 11. Round | 27/11/1966 | FC Barcelona | - | Hércules CF | 4:1 | ||||
| 12. Round | 04/12/1966 | Hércules CF | - | Deportivo La Coruña | 0:1 | ||||
| 27. Round | 02/04/1967 | Deportivo La Coruña | - | Hércules CF | 1:0 | ||||
| 28. Round | 09/04/1967 | Hércules CF | - | Valencia CF | 4:1 | ||||
| 29. Round | 16/04/1967 | Córdoba CF | - | Hércules CF | 1:1 | ||||
| 30. Round | 23/04/1967 | Hércules CF | - | Atlético Madrid | 2:4 |
Spain