| 1. Round | 19/08/2012 | FC Barcelona | - | Real Sociedad | 5:1 |  |
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| 2. Round | 25/08/2012 | Real Sociedad | - | RC Celta | 2:1 | |
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| 3. Round | 01/09/2012 | RCD Mallorca | - | Real Sociedad | 1:0 | |
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| 8. Round | 21/10/2012 | Real Sociedad | - | Atlético Madrid | 0:1 | |
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| 19. Round | 13/01/2013 | Real Sociedad | - | Deportivo La Coruña | 1:1 | |
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| 27. Round | 10/03/2013 | Atlético Madrid | - | Real Sociedad | 0:1 | ||||
| 33. Round | 28/04/2013 | Real Sociedad | - | Valencia CF | 4:2 | ||||
| 38. Round | 01/06/2013 | Deportivo La Coruña | - | Real Sociedad | 0:1 |
Spain