| 1. Round | 13/08/2022 | Real Valladolid | - | Villarreal CF | 0:3 | ||||
| 2. Round | 19/08/2022 | Sevilla FC | - | Real Valladolid | 1:1 | ||||
| 4. Round | 05/09/2022 | Real Valladolid | - | UD Almería | 1:0 | ||||
| 5. Round | 09/09/2022 | Girona FC | - | Real Valladolid | 2:1 | ||||
| 6. Round | 16/09/2022 | Real Valladolid | - | Cádiz CF | 0:1 | ||||
| 23. Round | 26/02/2023 | RC Celta | - | Real Valladolid | 3:0 | ||||
| 24. Round | 05/03/2023 | Real Valladolid | - | Espanyol Barcelona | 2:1 | ||||
| 25. Round | 11/03/2023 | Elche CF | - | Real Valladolid | 1:1 | ||||
| 26. Round | 17/03/2023 | Real Valladolid | - | Athletic Club | 1:3 | ||||
| 27. Round | 02/04/2023 | Real Madrid | - | Real Valladolid | 6:0 |
Spain