| 1. Round | 24/08/2024 | UD Ibiza | - | Villarreal CF B | 1:1 |  |
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| 2. Round | 01/09/2024 | Villarreal CF B | - | Real Betis B | 2:2 |  |
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| 10. Round | 27/10/2024 | Villarreal CF B | - | Real Murcia | 0:1 | ||||
| 16. Round | 08/12/2024 | Villarreal CF B | - | Marbella FC | 1:1 | ||||
| 38. Round | 24/05/2025 | Real Betis B | - | Villarreal CF B | 0:3 |
Mali