| 16. Round | 25/01/2023 | Madrid CFF [Women] | - | Atlético Madrid [Women] | 2:2 |  |
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| 17. Round | 29/01/2023 | Atlético Madrid [Women] | - | Sevilla FC [Women] | 1:1 | ||||
| 18. Round | 05/02/2023 | Sporting de Huelva [Women] | - | Atlético Madrid [Women] | 1:3 | ||||
| 19. Round | 12/02/2023 | Atlético Madrid [Women] | - | Athletic Club [Women] | 1:0 | ||||
| 20. Round | 04/03/2023 | Real Sociedad [Women] | - | Atlético Madrid [Women] | 1:2 | ||||
| 21. Round | 12/03/2023 | Atlético Madrid [Women] | - | Real Madrid [Women] | 0:0 | ||||
| 23. Round | 26/03/2023 | CD Alavés [Women] | - | Atlético Madrid [Women] | 1:2 | ||||
| 24. Round | 01/04/2023 | Atlético Madrid [Women] | - | Valencia CF [Women] | 6:2 | |
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| 25. Round | 15/04/2023 | FC Barcelona [Women] | - | Atlético Madrid [Women] | 4:0 | ||||
| 27. Round | 30/04/2023 | Real Betis [Women] | - | Atlético Madrid [Women] | 1:1 | ||||
| 28. Round | 06/05/2023 | Atlético Madrid [Women] | - | Levante Las Planas [Women] | 0:1 | ||||
| 29. Round | 13/05/2023 | Villarreal CF [Women] | - | Atlético Madrid [Women] | 1:1 | ||||
| 30. Round | 19/05/2023 | Atlético Madrid [Women] | - | UDG Tenerife Sur [Women] | 4:0 | |
Spain