| 1. Round | 04/09/1949 | Athletic Club | - | FC Barcelona | 3:1 |  |
|||
| 2. Round | 11/09/1949 | FC Barcelona | - | Gimnàstic de Tarragona | 10:1 | ||||
| 3. Round | 18/09/1949 | Real Madrid | - | FC Barcelona | 6:1 | ||||
| 4. Round | 25/09/1949 | FC Barcelona | - | Sevilla FC | 7:0 | |
|||
| 5. Round | 02/10/1949 | Deportivo La Coruña | - | FC Barcelona | 3:0 | ||||
| 14. Round | 11/12/1949 | FC Barcelona | - | Athletic Club | 5:0 | |
|||
| 15. Round | 18/12/1949 | Gimnàstic de Tarragona | - | FC Barcelona | 1:4 | |
|||
| 16. Round | 15/01/1950 | FC Barcelona | - | Real Madrid | 2:3 | |
|||
| 17. Round | 22/01/1950 | Sevilla FC | - | FC Barcelona | 5:2 | ||||
| 18. Round | 29/01/1950 | FC Barcelona | - | Deportivo La Coruña | 2:0 | ||||
| 19. Round | 05/02/1950 | Real Valladolid | - | FC Barcelona | 2:1 | ||||
| 20. Round | 12/02/1950 | Real Sociedad | - | FC Barcelona | 2:4 | |
|||
| 21. Round | 19/02/1950 | FC Barcelona | - | Real Oviedo | 5:0 | ||||
| 22. Round | 26/02/1950 | Valencia CF | - | FC Barcelona | 4:0 | ||||
| 23. Round | 05/03/1950 | FC Barcelona | - | Atlético Madrid | 1:0 | ||||
| 24. Round | 12/03/1950 | CD Málaga | - | FC Barcelona | 0:0 | ||||
| 25. Round | 16/04/1950 | FC Barcelona | - | RC Celta | 2:1 |
Spain