| 2. Round | 30/09/1945 | Sporting Gijón | - | Hércules CF | 2:0 | ||||
| 5. Round | 21/10/1945 | Hércules CF | - | Atlético Aviación | 3:2 | ||||
| 6. Round | 28/10/1945 | Athletic Club | - | Hércules CF | 6:0 | ||||
| 10. Round | 02/12/1945 | FC Barcelona | - | Hércules CF | 5:3 | ||||
| 11. Round | 09/12/1945 | Real Madrid | - | Hércules CF | 2:0 | ||||
| 23. Round | 10/03/1946 | Hércules CF | - | FC Barcelona | 0:0 | ||||
| 24. Round | 17/03/1946 | Hércules CF | - | Real Madrid | 2:3 | ||||
| 25. Round | 24/03/1946 | RC Celta | - | Hércules CF | 4:2 | ||||
| 26. Round | 31/03/1946 | Hércules CF | - | CD Castellón | 1:2 |
Spain