| 1. Round | 13/08/2022 | RC Celta | - | Espanyol Barcelona | 2:2 | ||||
| 2. Round | 19/08/2022 | Espanyol Barcelona | - | Rayo Vallecano | 0:2 | ||||
| 3. Round | 28/08/2022 | Espanyol Barcelona | - | Real Madrid | 1:3 |  |
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| 8. Round | 09/10/2022 | Cádiz CF | - | Espanyol Barcelona | 2:2 | ||||
| 9. Round | 16/10/2022 | Espanyol Barcelona | - | Real Valladolid | 1:0 | ||||
| 10. Round | 20/10/2022 | CA Osasuna | - | Espanyol Barcelona | 1:0 | ||||
| 11. Round | 23/10/2022 | Espanyol Barcelona | - | Elche CF | 2:2 | ||||
| 12. Round | 28/10/2022 | RCD Mallorca | - | Espanyol Barcelona | 1:1 | ||||
| 13. Round | 06/11/2022 | Atlético Madrid | - | Espanyol Barcelona | 1:1 |  |
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| 14. Round | 09/11/2022 | Espanyol Barcelona | - | Villarreal CF | 0:1 |
France