| 1. Round | 17/08/2019 | Bor. Mönchengladbach | - | FC Schalke 04 | 0:0 |  |
|||
| 2. Round | 24/08/2019 | FC Schalke 04 | - | Bayern München | 0:3 | ||||
| 3. Round | 31/08/2019 | FC Schalke 04 | - | Hertha BSC | 3:0 | ||||
| 4. Round | 15/09/2019 | SC Paderborn 07 | - | FC Schalke 04 | 1:5 | ||||
| 5. Round | 20/09/2019 | FC Schalke 04 | - | 1. FSV Mainz 05 | 2:1 | ||||
| 6. Round | 28/09/2019 | RB Leipzig | - | FC Schalke 04 | 1:3 | ||||
| 7. Round | 05/10/2019 | FC Schalke 04 | - | 1. FC Köln | 1:1 | ||||
| 8. Round | 20/10/2019 | 1899 Hoffenheim | - | FC Schalke 04 | 2:0 | ||||
| 9. Round | 26/10/2019 | FC Schalke 04 | - | Borussia Dortmund | 0:0 | |
France
Algeria 
