| 1. Round | 05/09/2021 | Real Sociedad [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 2. Round | 12/09/2021 | Valencia CF [Women] | - | Sporting de Huelva [Women] | 2:2 | ||||
| 3. Round | 25/09/2021 | FC Barcelona [Women] | - | Valencia CF [Women] | 8:0 | ||||
| 4. Round | 29/09/2021 | Valencia CF [Women] | - | Athletic Club [Women] | 1:3 | ||||
| 5. Round | 03/10/2021 | Valencia CF [Women] | - | Sevilla FC [Women] | 1:2 | ||||
| 25. Round | 26/03/2022 | Atlético Madrid [Women] | - | Valencia CF [Women] | 3:0 | ||||
| 24. Round | 30/03/2022 | Valencia CF [Women] | - | Villarreal CF [Women] | 2:1 | ||||
| 26. Round | 02/04/2022 | Athletic Club [Women] | - | Valencia CF [Women] | 2:2 |  |
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| 27. Round | 16/04/2022 | Valencia CF [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| 29. Round | 08/05/2022 | Valencia CF [Women] | - | Real Madrid [Women] | 0:0 |
Spain