| Primera | 01/02/59 | Sporting Gijón | - | CA Osasuna | 2:1 | ||||
| Primera | 04/10/64 | Real Oviedo | - | Espanyol Barcelona | 3:1 |  |
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| Primera | 08/11/64 | Real Oviedo | - | Valencia CF | 0:1 |
| Primera | 01/02/59 | Sporting Gijón | - | CA Osasuna | 2:1 | ||||
| Primera | 04/10/64 | Real Oviedo | - | Espanyol Barcelona | 3:1 | |
|||
| Primera | 08/11/64 | Real Oviedo | - | Valencia CF | 0:1 |
| Rafael Biempica Álvarez | |
| Born: | 02.05.1937 † 21.03.2020 |
| Place of birth: |
Gijón, 
Spain |
| Nationality: |
Spain
|