| 3. Round | 25/09/1966 | Hércules CF | - | Pontevedra CF | 1:0 | ||||
| 4. Round | 02/10/1966 | Espanyol Barcelona | - | Hércules CF | 4:1 | ||||
| 5. Round | 09/10/1966 | Hércules CF | - | Granada CF | 2:1 | ||||
| 6. Round | 16/10/1966 | Real Zaragoza | - | Hércules CF | 2:0 | ||||
| 7. Round | 30/10/1966 | Hércules CF | - | Sevilla FC | 2:1 | ||||
| 8. Round | 06/11/1966 | Real Madrid | - | Hércules CF | 2:1 | ||||
| 9. Round | 13/11/1966 | Hércules CF | - | UD Las Palmas | 2:1 | ||||
| 10. Round | 20/11/1966 | Hércules CF | - | Athletic Club | 1:2 | ||||
| 13. Round | 11/12/1966 | Valencia CF | - | Hércules CF | 4:0 | ||||
| 14. Round | 18/12/1966 | Hércules CF | - | Córdoba CF | 1:1 | ||||
| 24. Round | 12/03/1967 | UD Las Palmas | - | Hércules CF | 0:1 |
Spain