| 4. Round | 14/10/1945 | Espanyol Barcelona | - | RC Celta | 4:1 |  |
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| 5. Round | 21/10/1945 | CD Castellón | - | Espanyol Barcelona | 4:1 | |
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| 6. Round | 28/10/1945 | Espanyol Barcelona | - | Sevilla FC | 1:1 | ||||
| 7. Round | 04/11/1945 | Sporting Gijón | - | Espanyol Barcelona | 4:1 | ||||
| 10. Round | 02/12/1945 | Atlético Aviación | - | Espanyol Barcelona | 7:3 | |
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| 11. Round | 09/12/1945 | Espanyol Barcelona | - | Athletic Club | 1:5 | |
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| 12. Round | 16/12/1945 | Valencia CF | - | Espanyol Barcelona | 3:2 | |
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| 13. Round | 30/12/1945 | Espanyol Barcelona | - | Real Murcia | 0:1 | ||||
| 18. Round | 03/02/1946 | Espanyol Barcelona | - | CD Castellón | 4:1 | ||||
| 19. Round | 10/02/1946 | Sevilla FC | - | Espanyol Barcelona | 1:0 |
Spain