| 1. Round | 11/09/1960 | Real Valladolid | - | Real Oviedo | 3:0 | ||||
| 2. Round | 18/09/1960 | Real Oviedo | - | Real Betis | 2:1 | ||||
| 3. Round | 25/09/1960 | Racing Santander | - | Real Oviedo | 3:0 | ||||
| 4. Round | 02/10/1960 | Real Oviedo | - | Atlético Madrid | 0:0 | ||||
| 5. Round | 09/10/1960 | Real Sociedad | - | Real Oviedo | 2:0 | ||||
| 7. Round | 23/10/1960 | Espanyol Barcelona | - | Real Oviedo | 4:1 | ||||
| 8. Round | 06/11/1960 | Real Oviedo | - | Valencia CF | 2:2 | ||||
| 23. Round | 26/02/1961 | Valencia CF | - | Real Oviedo | 3:1 | ||||
| 25. Round | 12/03/1961 | Granada CF | - | Real Oviedo | 1:1 | ||||
| 26. Round | 19/03/1961 | Real Oviedo | - | Real Madrid | 0:0 |
Brazil