| 4. Round | 14/10/1945 | Athletic Club | - | Real Oviedo | 2:4 |  |
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| 5. Round | 21/10/1945 | Real Oviedo | - | Valencia CF | 3:0 | |
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| 6. Round | 28/10/1945 | Real Murcia | - | Real Oviedo | 0:3 | |
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| 7. Round | 04/11/1945 | Real Madrid | - | Real Oviedo | 3:1 | |
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| 8. Round | 18/11/1945 | Real Oviedo | - | FC Barcelona | 1:1 | ||||
| 9. Round | 25/11/1945 | Hércules CF | - | Real Oviedo | 0:3 | |
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| 10. Round | 02/12/1945 | Real Oviedo | - | RC Celta | 1:0 | ||||
| 11. Round | 09/12/1945 | CD Castellón | - | Real Oviedo | 1:1 | ||||
| 12. Round | 16/12/1945 | Real Oviedo | - | Sevilla FC | 1:1 | |
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| 13. Round | 30/12/1945 | Sporting Gijón | - | Real Oviedo | 1:0 | ||||
| 14. Round | 06/01/1946 | Espanyol Barcelona | - | Real Oviedo | 1:2 | |
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| 16. Round | 20/01/1946 | Atlético Aviación | - | Real Oviedo | 2:2 | ||||
| 17. Round | 27/01/1946 | Real Oviedo | - | Athletic Club | 1:2 | |
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| 18. Round | 03/02/1946 | Valencia CF | - | Real Oviedo | 2:2 | ||||
| 19. Round | 10/02/1946 | Real Oviedo | - | Real Murcia | 0:0 | ||||
| 20. Round | 17/02/1946 | Real Oviedo | - | Real Madrid | 1:1 | |
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| 23. Round | 10/03/1946 | RC Celta | - | Real Oviedo | 3:2 | |
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| 24. Round | 17/03/1946 | Real Oviedo | - | CD Castellón | 4:2 | |
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| 25. Round | 24/03/1946 | Sevilla FC | - | Real Oviedo | 3:0 |
Spain