| 2. Round | 11/09/1949 | Real Oviedo | - | Espanyol Barcelona | 2:3 |  |
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| 3. Round | 18/09/1949 | Athletic Club | - | Real Oviedo | 3:0 | ||||
| 4. Round | 25/09/1949 | Real Oviedo | - | Gimnàstic de Tarragona | 1:1 | ||||
| 5. Round | 02/10/1949 | Real Madrid | - | Real Oviedo | 6:2 | ||||
| 10. Round | 06/11/1949 | Real Oviedo | - | Real Valladolid | 2:2 | |
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| 14. Round | 11/12/1949 | Real Oviedo | - | RC Celta | 1:2 | ||||
| 20. Round | 12/02/1950 | Real Oviedo | - | Deportivo La Coruña | 0:2 | ||||
| 23. Round | 05/03/1950 | Real Valladolid | - | Real Oviedo | 2:2 | ||||
| 24. Round | 12/03/1950 | Valencia CF | - | Real Oviedo | 2:1 |
Spain