| 13. Round | 10/11/2013 | Real Betis | - | FC Barcelona | 1:4 | ||||
| 20. Round | 18/01/2014 | Real Betis | - | Real Madrid | 0:5 | ||||
| 28. Round | 16/03/2014 | Elche CF | - | Real Betis | 0:0 |
| 13. Round | 10/11/2013 | Real Betis | - | FC Barcelona | 1:4 | ||||
| 20. Round | 18/01/2014 | Real Betis | - | Real Madrid | 0:5 | ||||
| 28. Round | 16/03/2014 | Elche CF | - | Real Betis | 0:0 |
| José Antonio Caro Martínez | |
| Born: | 08.03.1993 |
| Place of birth: |
Estepa, 
Spain |
| Nationality: |
Spain
|
| Height: | 183 cm |
| Weight: | 70 kg |
| Position(s): | Centre Back Right Back |
| Foot: | right |