| Group I | 07/11/2013 | Vitória Guimarães | - | Real Betis | 0:1 | ||||
| Round of 32 | 27/02/2014 | Rubin Kazan | - | Real Betis | 0:2 | ||||
| Round of 16 | 13/03/2014 | Sevilla FC | - | Real Betis | 0:2 |  |
| Group I | 07/11/2013 | Vitória Guimarães | - | Real Betis | 0:1 | ||||
| Round of 32 | 27/02/2014 | Rubin Kazan | - | Real Betis | 0:2 | ||||
| Round of 16 | 13/03/2014 | Sevilla FC | - | Real Betis | 0:2 | |
| José Antonio Caro Martínez | |
| Born: | 08.03.1993 |
| Place of birth: |
Estepa, 
Spain |
| Nationality: |
Spain
|
| Height: | 183 cm |
| Weight: | 70 kg |
| Position(s): | Centre Back Right Back |
| Foot: | right |